My favorite, and I think the best way to raise rep.
A couple of points on regular quests for rep that a lot of people often overlook, or don’t know about:
1. Full rep, no matter what level you or the quest is. Even a lvl 70 will get full rep from a lvl 1 quest.
2. Spillover: most quests that gives C9 Online to any one of your 5 factions, will also give 1/4 of that rep to each of the other 4.
For example, if a quest gives 100 Stormwind rep, it will also give 25 rep to Ironforge, Gnomeregan, Darnassus, AND Exodar.
There is no ingame rep message that shows the Spillover rep, but the info is still there, in the form of all of those reps increasing. You can have a message show, if you want, by using a mod / addon, like "MyReputation", found on curse.com.
1/4 will often result in fractions. 10 rep to one and 2.5 to the others? Since you can’t actually show 0.5 rep, you’ll get 2 one time and then 3 the next, and alternate back and forth. It’s like it saves any C9 Gold till the next turnin, then combines them till they make a whole. 75 rep and 18.5, will be 18 and 19.
Do every single quest from lvl 1 up to at least lvl 20-30, in the first 2-3 starting zones of the faction you want rep with. Then go for Spillover rep, and do every single quest from lvl 1 up to at least lvl 20-30, in the first 2-3 starting zones of every other race on your side.
The problem can be finding all those lower lvl quests, since you can no longer see a big yellow ! exclamation mark once the quest is gray to you. I use a site like Wowhead.com to show quests that give a particular rep.
choose a faction, click on "Quests". sort the quests by level / zone, whatever.
This may become a bit C9 Online Gold in Wrath. We will reportedly be able to track quest givers on the minimap, just like we currently can certain other npc’s like trainers and vendors. No specific details from the beta yet, as to how well this may work.

Not all quests in other race’s starting areas will be available to you, tho. Some of them are race specific, and only available to the race of that area.
Then there are a few scattered quests that will actually give rep to either "Alliance" or "Horde".
example, if it says "500 rep Alliance", that means all 5 Alliance factions will get 500 rep each, instead of just 500 to 1 of them and 125 spillover to each of the other 4.
Now anyone should be able to reach Exalted with the faction of their choice, by the time they hit 30, or at least close to it.